Plotting data for a first-order reaction
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The rate of a first-order reaction is followed by spectroscopy, monitoring the absorbance of a colored reactant at 520  nm. The reaction occurs in a 1.00-cm sample cell, and the only colored species in the reaction has an extinction coefficient of 5.60 ×10^3 M^-1  cm^-1 at 520  nm. (a) Calculate the initial concentration of the colored reactant if the absorbance is 0.605 at the beginning of the reaction. (b) The absorbance falls to 0.250 at 30.0  min. Calculate the rate constant in units of s^-1
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